An international intercomparison exercise on passive samplers (DGT) for monitoring metals in marine waters under a regulatory context

In order to move forward in the acceptance of a novel contaminant monitoring technique (Diffusive Gradients in Thin-films: DGT) for assessment of marine water bodies, sensu the WFD, an Inter-Laboratories Comparison (ILC) exercise (nine Europeans laboratories) was organized in the framework of the Interreg Atlantic Area MONITOOL project, which focused on the use of the DGT technique for the measurement of WFD priority metals (Cd, Ni and Pb).

Reproducible results were obtained for each metal by several laboratories, supporting the assertion that DGT analysis can be performed satisfactorily by laboratories experienced in measuring metals at trace levels in marine environments, even if they have limited practice in DGT analysis.

According to the Z-score analysis, among the 9 participating laboratories, 3 had 100 % of satisfactory results for Cd, Ni, and Pb, 3 had >80 % satisfactory results and 2 had about 60 % satisfactory results.

This work highlights the need to clearly describe the DGT method in order to control sources of contamination during analytical steps, in particular the resin gel retrieval and the elution steps.

Such international intercomparison exercise is an important step to develop the laboratory network involved in DGT analysis and contributes to the improvement of data quality.

Keyword(s)

Interlaboratory exercise, Water framework directive, Passive sampling, DGT, Priority metals

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Gonzalez Jean-Louis, Amouroux Isabelle, Guesdon Stephane, Menet-Nedelec Florence, Ponzevera Emmanuel, Montero Natalia, Marras Barbara, Schintu Marco, Caetano Miguel, Correia dos Santos Margarida, Rodrigo Sanz Marta, Millán Gabet Vanessa, Rodríguez Jose German, Belzunce-Segarra María Jesús, Larreta Joana, Menchaca Iratxe, Bersuder Philippe, Bolam Thi, Regan Fiona, White Blánaid, Zhang Hao (2022). An international intercomparison exercise on passive samplers (DGT) for monitoring metals in marine waters under a regulatory context. Science Of The Total Environment. 847. 157499 (10p.). https://doi.org/10.1016/j.scitotenv.2022.157499, https://archimer.ifremer.fr/doc/00785/89747/

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