Metal concentrations in transitional and coastal waters measured by passive (Diffusive Gradients in Thin-films) and spot sampling: MONITOOL Project Dataset
| Type | Article | ||||||||
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| Date | 2024-04 | ||||||||
| Language | English | ||||||||
| Author(s) | Rodriguez Jose German1, Guesdon Stephane 2, Amouroux Isabelle3, Bersuder Philippe4, 5, Bolam Thi5, Brito Pedro6, Caetano Miguel6, Santos Margarida M. Correia Dos7, Desogus Alessandro8, Fones Gary R.9, Gonzalez Jean-Louis10, Larreta Joana1, Lebrun Luc11, Marras Barbara8, McHugh Brendan12, Menet Florence13, Menchaca Iratxe1, Gabet Vanessa Millan14, Monteiro Carlos E., Montero Natalia, Nolan Martin15, Regan Fiona15, Rodrigo Marta14, Rosa Nuno, Schintu Marco, Schmitt Anne16, Todde Debora, Warford Lee, White Blanaid, Zhang Hao17 |
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| Affiliation(s) | 1 : AZTI, Herrera Kaia, Portualdea z/g, 20110 Pasaia, Spain 2 : Ifremer, LITTORAL, Environmental Resources Laboratory (Pertuis Charentais), Avenue de Mus de Loup, 17390 La Tremblade, France 3 : Ifremer, Chemical Contamination of Marine Ecosystems Unit, Rue de l'Ile d'Yeu, 44300 Nantes, France 4 : 06240 Beausoleil, Alpes-Maritimes, France 5 : CEFAS, Centre for Environment, Fisheries and Aquaculture Science, Lowestoft Laboratory, Pakefield Road, Suffolk, Lowestoft NR33 0HT, UK 6 : Instituto Português do Mar e da Atmosfera (IPMA), Division of Oceanography and Marine Environment, Av. Dr. Alfredo Magalhães Ramalho, 6, 1495-165, Algés, Portugal 7 : Centro de Química Estrutural, Institute of Molecular Sciences, Instituto Superior Técnico, Av. Rovisco Pais, 1049-001 Lisboa, Portugal 8 : UNICA, Dipartimento di Scienze Mediche e Sanità Pubblica, Università degli studi di Cagliari, 09124 Cagliari, Italy 9 : University of Portsmouth, School of the Environment Geography and Geosciences, Burnaby Road, Portsmouth PO1 3QL, UK 10 : Ifremer, LITTORAL, Environmental Resources Laboratory (Provence-Azur-Corse), Zone Portuaire de Brégaillon, 83507 La Seyne/mer, France 11 : Ifremer, LITTORAL, Environmental Resources Laboratory (Bretagne Occidentale), Place de la Croix - 29900 Concarneau, France 12 : Marine Institute, Rinville, Oranmore, Galway, Ireland 13 : Ifremer, LITTORAL, Environmental Resources Laboratory (Normandie), Avenue du Général de Gaulle, 14520 Port‑en‑Bessin, France 14 : ITC, Instituto Tecnológico de Canarias, Playa de Pozo Izquierdo, S/N. CP: 35119, Sta. Lucía, Las Palmas, Spain 15 : DCU Water Institute, Dublin City University, Dublin 9, Ireland 16 : Ifremer, LITTORAL, Environmental Resources Laboratory (Morbihan Pays de Loire), Rue de l'Ile d'Yeu, 44300 Nantes, France 17 : Lancaster Environment Centre, Lancaster University, Lancaster LA14YQ, UK |
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| Source | Data In Brief (2352-3409) (Elsevier), 2024-04 , Vol. 53 , P. 110145 (8p.) | ||||||||
| DOI | 10.1016/j.dib.2024.110145 | ||||||||
| Keyword(s) | Stripping voltammetry, Inductively coupled plasma mass, spectrometry, Harbour, Metal speciation, EU Water Framework Directive, monitoring, seawater, DGT | ||||||||
| Abstract | The MONITOOL project (2017-2023) was carried out to describe the relationships between total dissolved and labile metal concentrations measured in spot water samples and in concurrently deployed Diffusive Gradients in Thin -films (DGTs) passive samplers, respectively. The ultimate aim was to adapt existing marine metal Environmental Quality Standards (EQS marine water ) for DGTs, enabling their use in the context of the European Directives (the Water Framework Directive (WFD) and the Marine Strategy Framework Directive (MSFD)). Time -integrated metal concentrations provided by DGTs, representing several days, are an advantage compared to conventional spot sampling, especially in highly dynamic systems, such as transitional waters. Hence, the MONITOOL project aimed to provide a robust database of dissolved and labile metal concentrations in transitional and coastal waters, based upon co -deployments of DGTs and collection of spot water samples at several sampling sites (England, France, Ireland, Italy, Northern Ireland, Portugal, Scotland and Spain), followed subsequently by DGT and water metal analysis. Samplings were carried out in 2018 and 2022, following agreed protocols developed in the framework of the project. The MONITOOL dataset includes metal concentrations from DGTs, measured with Inductively Coupled Plasma Mass Spectrometry (ICP-MS: Cd, Co, Cu, Fe, Mn, Ni, Pb, Zn) and in concurrently collected spot water samples by ICP-MS (Al, Cd, Co, Cu, Mn, Ni, Pb, Zn) and Anodic/Cathodic Stripping Voltammetry (ASV/CSV: Cd, Pb, Ni). Moreover, data on seawater physical -chemical parameters (salinity, temperature, dissolved oxygen, pH, turbidity, total suspended solids, dissolved organic carbon, and total organic carbon) is provided. This database presents the results obtained using, concurrently, different forms of sampling and analytical techniques, enabling the comparison of the results obtained by these strategies and allowing the adaptation of EQS in marine water (EQS marine water) to DGTs (EQS DGT), in the context of the WFD. Moreover, due to the large number of sampling sites, it could also be used for other types of research, such as those dealing with metal speciation or the determination of baseline levels. (c) 2024 The Authors. Published by Elsevier Inc. This is an open access article under the CC BY license ( http://creativecommons.org/licenses/by/4.0/ ) |
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