In this paper, we consider a general Mayer optimal control problem governed by a mono-input affine control system whose optimal solution involves a second-order singular arc (leading to chattering). The objective of the paper is to present a numerical scheme to approach the chattering control by controls with a simpler structure (concatenation of bang-bang controls with a finite number of switching times and first-order singular arcs). Doing so, we consider a sequence of vector fields converging to the drift such that the associated optimal control problems involve only first-order singular arcs (and thus, optimal controls necessarily have a finite number of bang arcs). Up to a subsequence, we prove convergence of the sequence of extremals to an extremal of the original optimal control problem as well as convergence of the value functions. Next, we consider several examples of problems involving chattering. For each of them, we give an explicit family of approximated optimal control problems whose solutions involve bang arcs and first-order singular arcs. This allows us to approximate numerically solutions (with chattering) to these original optimal control problems.